Substance Details
Classification information
(1)UN Number
3356
(2)Proper Shipping Name
OXYGEN GENERATOR, CHEMICAL
(3)Class or division
5.1
(4)Subsidiary risks
-
(5)Packing group
-
(6)Special provisions
(7a)Limited quantities
0
(7b)Excepted quantities
(15)EmS
Packing Information
(8)Packing instructions
(9)Packing provisions
-
(10)IBC Instructions
-
(11)IBC Provisions
-
(13)Tank instructions
-
(14)Tank provisions
-
Stowage and Segregation Information
(16a)Stowage and handling
(16b)Segregation
-
Properties and Observations

Oxygen generators, chemicals, are devices containing chemicals which, upon activation, release oxygen as a product of chemical reaction. Chemical oxygen generators are used for the generation of oxygen for respiratory support, e.g. in aircraft, submarines, spacecraft, bomb shelters and breathing apparatus. Oxidizing salts such as chlorates and perchlorates of lithium, sodium and potassium, which are used in chemical oxygen generators, evolve oxygen when heated. These salts are mixed (compounded) with a fuel, usually iron powder, to form a chlorate candle, which produces oxygen by continuous reaction. The fuel is used to generate heat by oxidation. Once the reaction begins, oxygen is released from the hot salt by thermal decomposition (a thermal shield is used around the generator). A portion of the oxygen reacts with the fuel to produce more heat which produces more oxygen, and so on. Initiation of the reaction can be achieved by a percussion device, friction device or electric wire.

Package labels and marks
5.1
For marking and labelling of packages, including IBCs see section 5.2.