Substance Details
Classification information
(1)UN Number
3236
(2)Proper Shipping Name
SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED
(3)Class or division
4.1
(4)Subsidiary risks
-
(5)Packing group
-
(6)Special provisions
(7a)Limited quantities
0
(7b)Excepted quantities
(15)EmS
Packing Information
(8)Packing instructions
(9)Packing provisions
-
(10)IBC Instructions
-
(11)IBC Provisions
-
(13)Tank instructions
-
(14)Tank provisions
-
Self Reactives
AZODICARBONAMIDE FORMULATION TYPE D, TEMPERATURE CONTROLLED
< 100
OP7
-
-
6)
2,2'-AZODI(2,4-DIMETHYL-4-METHOXYVALERONITRILE)
100
OP7
-5
+5
-
2,2'-AZODI(2,4-DIMETHYLVALERONITRILE)
100
OP7
+10
+15
-
2,2'-AZODI(2-METHYLBUTYRONITRILE)
100
OP7
+35
+40
-
4-(BENZYL(METHYL)AMINO)-3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE
100
OP7
+40
+45
-
2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM TETRAFLUOROBORATE
100
OP7
+30
+35
-
2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE
66
OP7
+40
+45
-
2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE
67 - 100
OP7
+35
+40
-
2,5-DIETHOXY-4-(PHENYLSULPHONYL)BENZENEDIAZONIUM ZINC CHLORIDE
67
OP7
+40
+45
-
2,5-DIMETHOXY-4-(4-METHYLPHENYLSULPHONYL)BENZENEDIAZONIUM ZINC CHLORIDE
79
OP7
+40
+45
-
4-DIMETHYLAMINO-6-(2-DIMETHYLAMINOETHOXY)TOLUENE-2-DIAZONIUM ZINC CHLORIDE
100
OP7
+40
+45
-
2-(N,N-ETHOXYCARBONYLPHENYLAMINO)-3-METHOXY-4-(N-METHYL-N-CYCLOHEXYLAMINO)BENZENEDIAZONIUM ZINC CHLORIDE
62
OP7
+35
+40
-
2-(N,N-ETHOXYCARBONYLPHENYLAMINO)-3-METHOXY-4-(N-METHYL-N-CYCLOHEXYLAMINO)BENZENEDIAZONIUM ZINC CHLORIDE
63 - 92
OP7
+40
+45
-
N-FORMYL-2-(NITROMETHYLENE)-1,3-PERHYDROTHIAZINE
100
OP7
+45
+50
-
2-(2-HYDROXYETHOXY)-1-(PYRROLIDIN-1-YL)BENZENE-4-DIAZONIUM ZINC CHLORIDE
100
OP7
+45
+50
-
3-(2-HYDROXYETHOXY)-4-(PYRROLIDIN-1-YL)BENZENEDIAZONIUM ZINC CHLORIDE
100
OP7
+40
+45
-
2-(N,N-METHYLAMINOETHYLCARBONYL)-4-(3,4-DIMETHYLPHENYLSULPHONYL)BENZENEDIAZONIUM HYDROGEN SULPHATE
96
OP7
+45
+50
-
4-NITROSOPHENOL
100
OP7
+35
+40
-
Stowage and Segregation Information
(16a)Stowage and handling
Category: D
SW1
Protected from sources of heat.
SW3
Shall be transported under temperature control.
(16b)Segregation
SG35
Stow "separated from" acids.
SG36
Stow "separated from" alkalis.
Properties and Observations

Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Soluble in water except:
AZODICARBONAMIDE FORMULATION TYPE D
2,2'-AZODI(2,4-DIMETHYL-4-METHOXYVALERONITRILE)
2,2'-AZODI(2,4-DIMETHYLVALERONITRILE)
2,2'-AZODI(2-METHYLBUTRYRONITRILE)
N-FORMYL-2-(NITROMETHYLENE)-1,3-PERHYDROTHIAZINE
4-NITROSOPHENOL
Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation.

Package labels and marks
4.1
For marking and labelling of packages, including IBCs see section 5.2.